ChemInform Abstract: Modelling of Solvent Effects on the Diels-Alder Reaction
✍ Scribed by C. CATIVIELA; J. I. GARCIA; J. A. MAYORAL; L. SALVATELLA
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 25 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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The activation and reaction volumes (∆V /∆V) were showing negative volumes of activation (∆V Ͻ 0) whereas the others are slightly retarded (∆V Ͼ 0). From the analysis determined for the retro Diels-Alder reactions of the parent dihydrobarrelene 1a, its 2-cyano derivative 1b, the exo and of the volum
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