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Catalytic conversion of alcohol to corresponding alkyl chlorides

โœ Scribed by Chen Zhang-ping; Zhang Xuan; Li Xue-lian; Wu Xuan-jie


Publisher
Wuhan University
Year
2000
Tongue
English
Weight
61 KB
Volume
5
Category
Article
ISSN
1007-1202

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A useful conversion of alcohols to alkyl
โœ David A Flosser; Roy A Olofson ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 113 KB

A useful conversion of alcohols to alkyl fluorides via their fluoroformates is introduced. The fluoroformates are obtained in nearly quantitative yield from the alcohols by treatment with COF 2 (generated in situ from bis(trichloromethyl) carbonate) in ether with KF as an added acid scavenger. The n