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Conversion of Hydrazones to Alkyl Chlorides under Swern Oxidation Conditions.

✍ Scribed by Matthias Brewer


Publisher
John Wiley and Sons
Year
2007
Weight
20 KB
Volume
38
Category
Article
ISSN
0931-7597

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Synthesis of oximes, conversion to nitri
✍ BΓ©atrice Touaux; FranΓ§oise Texier-Boullet; Jack Hamelin πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 147 KB πŸ‘ 1 views

Aldoximes and ketoximes were readily synthesized from aldehydes and hydroxylamine hydrochloride on Al 2 O 3 without solvent under microwave irradiation. At higher irradiation power, aldoximes dehydrated to nitriles and ketoximes rearranged to amides. Aldoximes reacted in a one-pot reaction with Nchl