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Catalytic Carbon−Carbon Bond Activation and Functionalization by Nickel Complexes

✍ Scribed by Edelbach, Brian L.; Lachicotte, Rene J.; Jones, William D.


Book ID
127092691
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
132 KB
Volume
18
Category
Article
ISSN
0276-7333

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## Abstract Monocoordinate nickel/__N__‐heterocyclic carbene complexes reveal unexpected reactivity towards aryl fluorides. Defluorination reactions were efficiently performed with a β‐hydrogen‐containing alkoxide (3 equiv.) in the presence of 3 mol % of [1:1] Ni(0)/IMes⋅HCl catalyst (IMes=1,3‐dime