𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Catalytic applications of F8BINOL: asymmetric oxidation of sulfides to sulfoxides

✍ Scribed by L.James P Martyn; Subramanian Pandiaraju; Andrei K Yudin

Book ID
108346636
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
123 KB
Volume
603
Category
Article
ISSN
0022-328X

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Catalytic asymmetric oxidation of sulfid
Catalytic asymmetric oxidation of sulfides to sulfoxides using R-(+)-binaphthol
✍ Naoki Komatsu; Yoshiaki Nishibayashi; Toshio Sugita; Sakae Uemura πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 French βš– 173 KB

An asymmetric oxidation system using R-(+)-binaphthol as a chiral auxiliary catalyzes the oxidation of sulfides to chiral sulfoxides in good Β’nantiomeric excess ( up to 73% e.e. ) and in a high chemical yield. Although the chiral binaphthol derivatives have been used as an effective chiral auxiliar

An efficient asymmetric oxidation of sul
An efficient asymmetric oxidation of sulfides to sulfoxides
✍ Philippe Pitchen; Henri B. Kagan πŸ“‚ Article πŸ“… 1984 πŸ› Elsevier Science 🌐 French βš– 240 KB

The Sharpless reagent (Ti(OiPr)4 t 1 mol eq. diethyl tartrate (DET) t 2 J-BuOOH) modified by addition of one mol eq. H20 gives a new homogeneous reagent which cleanly oxidizes sulfidesinto sulfoxides in dichloromethane. The best results were obtained for the stoichiometry Ti/DET/ H20/J-BuOOH = 1:2:1