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Applications of Catalytic Asymmetric Sulfide Oxidations to the Syntheses of Biologically Active Sulfoxides

✍ Scribed by Julien Legros; Juan R. Dehli; Carsten Bolm

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
216 KB
Volume
347
Category
Article
ISSN
1615-4150

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Catalytic diastereoselective sulfimidati
Catalytic diastereoselective sulfimidation of diaryl sulfides and application of chiral sulfimides to asymmetric allylic alkylation
✍ Hiroya Takada; Masamitsu Oda; Arihiro Oyamada; Kouichi Ohe; Sakae Uemura 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 364 KB 👁 1 views

The copper-catalyzed diastereoselective imidation of diaryl sulfides bearing a chiral oxazolinyl moiety at the ortho-position with [N-(p-toluenesulfonyl) imino]phenyliodinane (TsN=IPh) or Chloramine-T trihydrate [TsN(Cl)Na.3H2O] was successfully carried out to give the corresponding optically active