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Application of Chiral Sulfides to Catalytic Asymmetric Aziridination and Cyclopropanation with In Situ Generation of the Diazo Compound

✍ Scribed by Varinder K. Aggarwal; Emma Alonso; Guangyu Fang; Marco Ferrara; George Hynd; Marina Porcelloni


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
82 KB
Volume
40
Category
Article
ISSN
0044-8249

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Catalytic Asymmetric Aziridination of En
✍ Waldemar Adam; Konrad Johann Roschmann; Chantu Ranjan Saha-Möller 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 292 KB 👁 1 views

A series of acyclic and cyclic enol derivatives 1 has been transformed into the corresponding α-amino-functionalized ketones 2 by means of enantioselective catalytic aziridination with chiral Cu complexes, prepared in situ from [Cu(MeCN)4]PF 6 and the optically active ligands 3, by using (N-tosylimi