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Catalytic Asymmetric Oxidation of Sulfides to Sulfoxides Mediated by Chiral 3-Substituted-1,2-benzisothiazole 1,1-Dioxides.

โœ Scribed by Bethell, Donald; Page, Philip C. Bulman; Vahedi, Hooshang


Book ID
125902719
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
6 KB
Volume
65
Category
Article
ISSN
0022-3263

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Catalytic asymmetric oxidation of aryl m
โœ Stefano Superchi; Carlo Rosini ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 238 KB

The asymmetric oxidation of aryl methyl sulfides to sulfoxides with hydroperoxides has been achieved using catalytic amounts of the complex formed in situ between Ti(i-PrO) 4, (S,S)-diphenylethan-l,2-diol 1 and water. The sulfoxides are obtained in 60% yield and 67-80% enantiomeric excess.