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Catalyst-Controlled Diastereoselective Hetero-Diels−Alder Reactions

✍ Scribed by Joly, Guy D.; Jacobsen, Eric N.

Book ID
120886757
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
58 KB
Volume
4
Category
Article
ISSN
1523-7060

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Indium triflate-an efficient catalyst fo
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✍ Tayyeb Ali; Kamlesh K. Chauhan; Christopher G. Frost 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 182 KB

At a loading as low as 0.5 mol% indium triflate has been found to catalyse the hetero Diels-Alder reaction. A three component coupling reaction between aldehydes, amines and Danishefsky's diene to afford tetrahydropyridine derivatives proceeds similarly in high yield.