Indium triflate-an efficient catalyst for hetero Diels-Alder reactions
β Scribed by Tayyeb Ali; Kamlesh K. Chauhan; Christopher G. Frost
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- French
- Weight
- 182 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
β¦ Synopsis
At a loading as low as 0.5 mol% indium triflate has been found to catalyse the hetero Diels-Alder reaction. A three component coupling reaction between aldehydes, amines and Danishefsky's diene to afford tetrahydropyridine derivatives proceeds similarly in high yield.
π SIMILAR VOLUMES
## TrijZuoromethonesu~onic (trif7ic)acid (1 rmrl%)has beenfound to be an eficient catalystfor the hetero Diels-Alder reactionbetweenaromaticaldehy&s and unuctivateddienes.@ 1997ElsevierScienceLtd.
Indium trichloride (20 mol%) in nitromethane permits ionic Diels-Alder reaction of a variety of 2,3-olefinic acetals to form the corresponding cycloadducts in good yields with good endo selectivities.