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Highly Enantio- and Diastereoselective Hetero-Diels–Alder Reactions Catalyzed by New Chiral Tridentate Chromium(III) Catalysts

✍ Scribed by Alexander G. Dossetter; Timothy F. Jamison; Eric N. Jacobsen


Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
101 KB
Volume
38
Category
Article
ISSN
0044-8249

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ChemInform Abstract: Asymmetric Hetero-D
✍ S. E. SCHAUS; J. BRAANALT; E. N. JACOBSEN 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB

Asymmetric Hetero-Diels-Alder Reactions Catalyzed by Chiral (Salen)Chromium(III) Complexes. -The title reactions between (I) and a wide range of aldehydes require only 2 mol% of the catalyst and afford the pyranone derivatives (III) with good enantioselectivity. Among different derivatives of the c