✦ LIBER ✦

Catalysis of Diels-Alder reactions by metalloporphyrins

✍ Scribed by David W. Bartley; Thomas J. Kodadek

Publisher: Elsevier Science
Year: 1990
Tongue: French
Weight: 191 KB
Volume: 31
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)97048-5

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✦ Synopsis

Aluminium (III) tetraphenyl porphyrin chloride (AITPPCI) has been shown to catalyze Diels-Alder reactions of a&unsaturated carbonyl.compounds in moderate yield. Wdivity based on electronic effects is exhibited which is different from that seen with catalysts such as diethylaluminium chloride.

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