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Heterogeneous catalysis of asymmetric Diels—Alder reactions

✍ Scribed by Carlos Cativiela; José M. Fraile; José I. García; José A. Mayoral; Elisabet Pires; François Figueras


Publisher
Elsevier Science
Year
1994
Weight
334 KB
Volume
89
Category
Article
ISSN
0304-5102

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Aluminium (III) tetraphenyl porphyrin chloride (AITPPCI) has been shown to catalyze Diels-Alder reactions of a&unsaturated carbonyl.compounds in moderate yield. Wdivity based on electronic effects is exhibited which is different from that seen with catalysts such as diethylaluminium chloride.