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Catalysis by temporary covalent activation. A novel catalysis of unactivated Diels-Alder reactions

✍ Scribed by Daniel A. Singleton; Shun-Wang Leung; Jose P. Martinez; Yu-Kai Lee

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
173 KB
Volume
38
Category
Article
ISSN
0040-4039

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ChemInform Abstract: Catalysis by Tempor
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Aluminium (III) tetraphenyl porphyrin chloride (AITPPCI) has been shown to catalyze Diels-Alder reactions of a&unsaturated carbonyl.compounds in moderate yield. Wdivity based on electronic effects is exhibited which is different from that seen with catalysts such as diethylaluminium chloride.