Catalysis of Aryl Ester Hydrolysis in the Presence of Metallomicelles Containing a Copper(II) Diethylenetriamine Derivative
โ Scribed by Polyzos, Anastasios; Hughes, Andrew B.; Christie, John R.
- Book ID
- 120385662
- Publisher
- American Chemical Society
- Year
- 2007
- Tongue
- English
- Weight
- 103 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0743-7463
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๐ SIMILAR VOLUMES
Asymmetric polymers containing metal-chelating (S)-hydroxyproline groups in cross-linked polystyrene (I) and acrylamide (ll) matrices were used as catalysts for hydrolysis of or-amino acid esters. The hydrolysis catalysed by polymers I and II, complexed with Cu and Ni ions, displayed in many cases s
Aquocomplexes of cobalt(II), cobalt(III), palladium(II) and platinum(II) involving (HzNCH2)2, [H2N(CH2)z]2NH and [H2N(CHz)2NHCH2]2 as ligands were prepared and characterized. The kinetics of base hydrolysis of the amino acid esters HzNCH2CO2Me'HC1, HOC6H4CH2CH-(NHz)CO2Me-HCI, MeS(CH z)2CH(NH2)CO zMe