Ternary complexes of copper(II) involving diethylenetriamine and their role in the promotion of hydrolysis of α-amino acid esters
✍ Scribed by Mohamed M. Shoukry; Ezzat M. Khairy; Adel Saeed
- Publisher
- Springer
- Year
- 1988
- Tongue
- English
- Weight
- 499 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0340-4285
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The formation equilibria of the binary and ternary complexes of Cu n with N-(acetamido)-iminodiacetic acid (ADA) and amino acids or their esters were investigated potentiometrically. The chelation mode was ascertained by conductivity measurements. The kinetics of the base hydrolysis of amino acid es
Aquocomplexes of cobalt(II), cobalt(III), palladium(II) and platinum(II) involving (HzNCH2)2, [H2N(CH2)z]2NH and [H2N(CHz)2NHCH2]2 as ligands were prepared and characterized. The kinetics of base hydrolysis of the amino acid esters HzNCH2CO2Me'HC1, HOC6H4CH2CH-(NHz)CO2Me-HCI, MeS(CH z)2CH(NH2)CO zMe