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Catalysis in Water: A Viable Alternative for Asymmetric Transfer Hydrogenation of Ketones

✍ Scribed by Jianliang Xiao; Xiaofeng Wu; Antonio Zanotti-Gerosa; Fred Hancock


Publisher
John Wiley and Sons
Year
2007
Weight
11 KB
Volume
38
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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## Abstract A new polyethylene glycol‐supported chiral monosulfonamide was synthesized from (__R__,__R__)‐1,2‐diaminocyclohexane and shown to act as a ligand for ruthenium(II)‐catalyzed asymmetric transfer hydrogenation of aromatic ketones in neat water using sodium formate as the hydrogen source.