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Catalysis in ester cleavage. IV. One-proton solvation bridge intramolecular carboxylate catalysis of ester hydrolysis

✍ Scribed by Minor, Stephen S.; Schowen, Richard L.


Book ID
127326997
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
356 KB
Volume
95
Category
Article
ISSN
0002-7863

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Rate constants have been determined for hydrolysis of the acetate, glutarate, and phthalate monoesters of 2-hydroxy-1,10-phenanthroline in water at 30 degrees C and &mgr = 0.1 M with KCl. The hydrolysis reactions of the esters are hydroxide ion catalyzed at pH > 9. The phthalate and glutarate monoes