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Intramolecular bifunctional catalysis of ester hydrolysis by metal ion and carboxylate in the carboxypeptidase model

โœ Scribed by Breslow, Ronald; McAllister, Craig


Book ID
126941966
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
278 KB
Volume
93
Category
Article
ISSN
0002-7863

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Rate constants have been determined for hydrolysis of the acetate, glutarate, and phthalate monoesters of 2-hydroxy-1,10-phenanthroline in water at 30 degrees C and &mgr = 0.1 M with KCl. The hydrolysis reactions of the esters are hydroxide ion catalyzed at pH > 9. The phthalate and glutarate monoes