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One- and Two-Metal Ion Catalysis of the Hydrolysis of Adenosine 3‘-Alkyl Phosphate Esters. Models for One- and Two-Metal Ion Catalysis of RNA Hydrolysis

✍ Scribed by Bruice, Thomas C.; Tsubouchi, Akira; Dempcy, Robert O.; Olson, Leif P.


Book ID
120022628
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
360 KB
Volume
118
Category
Article
ISSN
0002-7863

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Rate constants have been determined for hydrolysis of the acetate, glutarate, and phthalate monoesters of 2-hydroxy-1,10-phenanthroline in water at 30 degrees C and &mgr = 0.1 M with KCl. The hydrolysis reactions of the esters are hydroxide ion catalyzed at pH > 9. The phthalate and glutarate monoes