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Carboxylate-Assisted Ruthenium-Catalyzed Direct Alkylations of Ketimines

✍ Scribed by Ackermann, Lutz; Hofmann, Nora; Vicente, Rubén

Book ID
118250771
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
985 KB
Volume
13
Category
Article
ISSN
1523-7060

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Described herein is the Rh I -catalyzed ortho-alkylation of aromatic ketimines or ketones with olefins. This method showed high reactivity and selectivity to monoalkylation for a variety of olefins including 1-alkenes with an allylic proton, a,w-dienes, and internal olefins. For a mechanistic study,