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ChemInform Abstract: Carboxylate-Assisted Ruthenium-Catalyzed Direct Alkylations of Ketimines.

✍ Scribed by Lutz Ackermann; Nora Hofmann; Ruben Vicente

Publisher: John Wiley and Sons
Year: 2011
Weight: 52 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201127056

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✦ Synopsis

Abstract

The presence of the sterically hindered 1‐adamantyl carboxylic acid as co‐catalyst is crucial for the high yields.The reaction is broadly applicable and the regioselectivity of the meta‐substituted arenes strongly depends on the steric effects.

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