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Carbonylation of n-alkylallylamines with CO/H2 mixtures

✍ Scribed by Alexandr Jegorov; Tomáš Trnka; František Tureček; Vladimír Hanuš

Publisher
Elsevier Science
Year
1990
Weight
529 KB
Volume
63
Category
Article
ISSN
0304-5102

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✍ Roberto A. Sánchez-Delgado; Ricardo Gomes da Rosa; Edgar Ocando-Mavarez 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 437 KB

The carbonylation and cyclization of N-alkylallylamines to y-butyrolactams is efficiently achieved by use of RhCI, 3H20/PPh, or RhCl(COXPPh,), as catalyst precursors under mild conditions (7O"C, 10 bar) when CO/H, (4: 1) mixtures are used instead of pure CO. Mechanistic studies on the Rh and the ana