Carbonyl olefination reaction using silyl-substituted organometallic compounds
β Scribed by Peterson, Donald John
- Book ID
- 115496113
- Publisher
- American Chemical Society
- Year
- 1968
- Tongue
- English
- Weight
- 728 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
**In order to check whether organic compounds can be nucleophilically silylated with Me~3~Siο£ΏAl compounds such as __(1)__ and __(2)__**, the latter were allowed to react with an aldehyde, a ketone, and an acid. Complexing agents like diethyl ether and AlCl~3~ have considerable influence on the react
It was found that rhenium complex is an effective catalyst for the reaction of carbonyl compounds with ketene silyl acetals. A wide range of b-silyloxy esters is obtained by the treatment of carbonyl compounds with ketene silyl acetals in the presence of a catalytic amount of ReBr(CO) 5 in moderate