𝔖 Bobbio Scriptorium
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Synthesis of Olefins from α-Silyl Carbanions and Carbonyl Compounds

✍ Scribed by Dr. Willy Dumont; Prof. Dr. Alain Krief

Publisher
John Wiley and Sons
Year
1976
Tongue
English
Weight
112 KB
Volume
15
Category
Article
ISSN
0044-8249

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Facile Syntheses of α-Bromo-α-silyl Ketones and α-Bromoacylsilanes from tert-Butyldimethylsilyldibromomethane and Carbonyl Compounds. -The synthesis of title compounds such as (III) and (V) and their usefulness is shown. The Tbs-group plays a critical role in the formation of these products. Mechan