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ChemInform Abstract: Facile Syntheses of α-Bromo-α-silyl Ketones and α- Bromoacylsilanes from tert-Butyldimethylsilyldibromomethane and Carbonyl Compounds.

✍ Scribed by H. SHINOKUBO; K. OSHIMA; K. UTIMOTO

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

Facile Syntheses of α-Bromo-α-silyl Ketones and α-Bromoacylsilanes from tert-Butyldimethylsilyldibromomethane and Carbonyl Compounds.

-The synthesis of title compounds such as (III) and (V) and their usefulness is shown. The Tbs-group plays a critical role in the formation of these products. Mechanistical aspects are discussed on the basis of further experiments.

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