Reactions of [RhClL] (L,=diolefin or (CO)(PPh,)) with the deprotonated form of the ligand 3,5bis(pyridin-2-yl)-1,2,4-triazole (Hbpt) gave neutral, mononuclear complexes [Rh&)(bpt)]. Cationic, mono-and dinuclear species of formulae [Rh&.)(Hbpt)]+, [{Rhb}\*(bpt)]+ and [{Rh&.}@bpt)]\*+, where b=diolefi
Carbonyl-molybdenum complexes of the hydrotris(3,5-dimethyl-1,2,4-triazol-1-yl) borate ligand
โ Scribed by Ian T. Macleod; Edward R.T. Tieknik; Charles G. Young
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 518 KB
- Volume
- 506
- Category
- Article
- ISSN
- 0022-328X
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๐ SIMILAR VOLUMES
The Schiff bases 3a-h obtained from 4-amino-1,2,4-triazol-3-ones 1a-h when subjected to Japp-Klingemann reaction yielded the corresponding 3-{2-[(2-aryl-5-methyl-3H-[1,2,4]-triazol-3-one-4-yl)]-iminophenyl}-pentane-2,4-diones 4 a-h. These diones on cyclisation with N 2 H 4 yielded the title compound
A method for the synthesis of heterecyclic ring conjugates containing 1,2,3-thiadiazole and 1,2,3-triazole nuclei was elaborated. The mechanism of rearrangement (effect of substituents and solvents) was investigated by NMR spectroscopy. A novel domino-type rearrangement involving both heterocycles w
## Abstract For Abstract see ChemInform Abstract in Full Text.