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Carbonyl insertion into a CS bond and complex dimerization during reaction of the dithioesters SC(Me)SEt and SC(Ph)SMe with iron carbonyl complexes

✍ Scribed by Gert J. Kruger; Antonie van A. Lombard; Helgard G. Raubenheimer

Publisher: Elsevier Science
Year: 1987
Tongue: English
Weight: 865 KB
Volume: 331
Category: Article
ISSN: 0022-328X
DOI: 10.1016/0022-328x(87)80026-8

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## Abstract The preparation and spectroscopic properties of new dipyrido[3,2‐__a__:2′,3′‐__c__]phenazine ruthenium complexes are described. The complexes show high catalytic activity in the water gas shift reaction in a basic medium under mild conditions (__P__~CO~ = 0.9 atm at 100 °C). Copyright ©