Synthesis of ruthenium complexes with carbonyl and polypyridyl ligands derived from dipyrido[3,2-a:2′,3′-c]phenazine: application to the water gas shift reaction

✍ Scribed by P. Aguirre; R. López; D. Villagra; I. Azocar-Guzman; A. J. Pardey; S. A. Moya

• Publisher: John Wiley and Sons
• Year: 2002
• Tongue: English
• Weight: 154 KB
• Volume: 17
• Category: Article
• ISSN: 0268-2605
• DOI: 10.1002/aoc.385

✦ Synopsis

Abstract

The preparation and spectroscopic properties of new dipyrido[3,2‐a:2′,3′‐c]phenazine ruthenium complexes are described. The complexes show high catalytic activity in the water gas shift reaction in a basic medium under mild conditions (P~CO~ = 0.9 atm at 100 °C). Copyright © 2002 John Wiley & Sons, Ltd.