✦ LIBER ✦

Dithioformate Fe(η2-HC(SR)S) complexes, and cleavage of the coordinated CS bond by alkynes. A route to FeCH(SR)COC(CO2Me)C(CO2Me)S(CO)(PR3)2 complexes

✍ Scribed by Daniel Touchard; Jean-Luc Fillaut; Pierre H. Dixneuf; Richard D. Adams; Brigitte E. Segmüller

Publisher: Elsevier Science
Year: 1990
Tongue: English
Weight: 1011 KB
Volume: 386
Category: Article
ISSN: 0022-328X
DOI: 10.1016/0022-328x(90)80259-3

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

The cleavage of a coordinated SCNR group

The cleavage of a coordinated SCNR group in [Fe(CO)2L2(η2-SCNR)] by [Co(η-C5H5)(PPh3)2] to give complexes containing μ3-CNR ligand. The preparation and structure of [{Co(η-C5H5)}2{Fe(CO)2(PPh3)}(μ3-S){μ3-CNC(O)C6H5}]

✍ Anthony R. Manning; Liam O'Dwyer; Patrick A. McArdle; Desmond Cunningham 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 148 KB

The preparation of the mixed thiolato-is

The preparation of the mixed thiolato-isocyanide complexes cis- and trans-(η5-C5H5)W(CO)2 (SR)(CNR′): the structure of trans-(η5-C5H5)W(CO)2(S-4-C6H4Me)(CNCMe3)

✍ Alan Shaver; Rosemary C. Hynes; Darlene Trojansek 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 576 KB

Synthesis, characterization, and electro

Synthesis, characterization, and electrochemistry of the mono- and bi-dentate xanthate complexes η5-C5R5Fe(CO)(η1-SC(S)OEt)L and η5-C5R5Fe(η2-S2COEt) L (R = H, Me; L = PBu3, PPh3, P(OEt)3, P(OPh)3)

✍ M. Morán; I. Cuadrado; J.R. Masaguer; J. Losada 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 960 KB

Antiferromagnetic complexes with a metal

Antiferromagnetic complexes with a metal—metal bond: XIII. Transformation of μ3-sulphide clusters containing chromium and cobalt atoms by treatment with pivalic acid. Molecular structures of the pseudotetrahedral cluster Cp3Cr3(μ3-S)3(μ3-O)Co(CO)3 · Me3CCOOH · 0.5C6H6, and the heterometallic “bow-tie” cluster (Cp2Cr2SCMe3)2(μ3-S)4Co

✍ I.L. Eremenko; A.A. Pasynskii; G.Sh. Gasanov; B. Orazsakhatov; Yu.T. Struchkov; 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 701 KB

Structural Characterization and Intramol

Structural Characterization and Intramolecular Aliphatic C−H Oxidation Ability of MIII(μ-O)2MIII Complexes of Ni and Co with the Hydrotris(3,5-dialkyl-4-X-pyrazolyl)borate Ligands Tp3.0.CO;2-C/asset/equation/tex2gif-sup-3.gif?v=1&t=h5lp536o&s=a03c9eb1fe277a993afb16d61a4b5e5e1fd6ae14" class="inlineGraphic"> (X=Me, H, Br) and Tp3.0.CO;2-C/asset/equation/tex2gif-sup-4.gif?v=1&t=h5lp536o&s=f62756419e66415fd41eb92c51dc480468265b22" class="inlineGraphic">

✍ Shiro Hikichi; Michito Yoshizawa; Yasuyuki Sasakura; Hidehito Komatsuzaki; Yoshi 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 531 KB

The nickel complex 2 Ni shows reactivity about 10 3 times greater than that of the cobalt analogue 2 Co . The oxidation ability of the M III (m-O) 2 M III core should be affected by the hindered Tp R ligand system, which can stabilize the 2 oxidation state of the metal centers.