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Carbonium Ion Rearrangements. V. 11,3-Hydride Shifts in the 1-Propyl Cation

โœ Scribed by Karabatsos, Gerasimos J.; Orzech, Chester E.

Book ID
126259365
Publisher
American Chemical Society
Year
1962
Tongue
English
Weight
257 KB
Volume
84
Category
Article
ISSN
0002-7863

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Evidence for a carbonium ion rearrangeme
Evidence for a carbonium ion rearrangement in the reaction of triisobutylaluminum and 1,3,3-trimethylcyclopropene
โœ Herman G. Richey Jr.; Barry Kubala; Mark A. Smith ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 212 KB

Formation of acyclic products in the reaction of triisobutylaluminum and 1,3,3trimethylcyclopropene can reasonably be ascribed to a carbonium ion rearrangement. This suggestion supports the mechanism for carbalumination of alkenes proposed by Eisch.