Classical carbonium ions. Part IV. Absence of hydride shift in the solvolysis of 1- and 2-adamantyl toluene-p-sulphonate

Deuterium isotope effects in the formoly

Deuterium isotope effects in the formolysis of threo-1-methyl-2-p-tolylpropyl toluene-p-sulphonate and the question of non-classical carbonium ion intermediates

✍ Spyro L. Loukas; Fannie S. Varveri; Margaret R. Velkou; George A. Gregoriou 📂 Article 📅 1971 🏛 Elsevier Science 🌐 French ⚖ 182 KB

The polarimetric formolysis rate constants for (+I-threo-1-methyl-2-p-tolylpropyl toluene-psulphonate H3C3\*C2H(C6H4CH3)\*C1H(CH3)0Ts (I), and the deuteriated derivatives H2,C~CH(C6H4CH31\*CH(CD3)OTs