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Deuterium isotope effects in the formolysis of threo-1-methyl-2-p-tolylpropyl toluene-p-sulphonate and the question of non-classical carbonium ion intermediates

✍ Scribed by Spyro L. Loukas; Fannie S. Varveri; Margaret R. Velkou; George A. Gregoriou


Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
182 KB
Volume
12
Category
Article
ISSN
0040-4039

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✦ Synopsis


The polarimetric formolysis rate constants for (+I-threo-1-methyl-2-p-tolylpropyl toluene-psulphonate H3C3*C2H(C6H4CH3)*C1H(CH3)0Ts (I), and the deuteriated derivatives H2,C~CH(C6H4CH31*CH(CD3)OTs