Stable, Free, Dianionic Silicon-Carbon Clusters. -Theoretical investigations (HF-SCF) on the electronic and structural stability of the cluster anions (I) and (II) show that both clusters exhibit vertical as well as adiabatic electronic stability and, hence, should be observable by mass spectrometr
✦ LIBER ✦
Carbon anions and dianion clusters
✍ Scribed by Roy Middleton; Jeff Klein
- Book ID
- 114168632
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 643 KB
- Volume
- 123
- Category
- Article
- ISSN
- 0168-583X
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## Abstract Phosphino‐stabilized allyl anions are formed by deprotonation of phosphinopropenes with alkyllithium. A double deprotonation of 2‐diphenylphosphinomethyl‐3‐diphenylphosphinopropene leads to interesting phosphino‐stabilized trimethylenemethane dianions. Alkylation with methyl iodide occu