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Phosphino-stabilized allyl anions and trimethylenemethane dianions

✍ Scribed by J. A. van Doom; H. van der Heijden

Book ID
104589177
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
179 KB
Volume
109
Category
Article
ISSN
0165-0513

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✦ Synopsis

Abstract

Phosphino‐stabilized allyl anions are formed by deprotonation of phosphinopropenes with alkyllithium. A double deprotonation of 2‐diphenylphosphinomethyl‐3‐diphenylphosphinopropene leads to interesting phosphino‐stabilized trimethylenemethane dianions. Alkylation with methyl iodide occurs at a carbon atom and not at a phosphorus centre.

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