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Carbon-13 NMR studies of a series of benzylphenols

✍ Scribed by Yoshimi Nakai; Fukiko Yamada

Publisher
John Wiley and Sons
Year
1978
Tongue
English
Weight
425 KB
Volume
11
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

Carbon‐13 NMR spectra of a series of benzylphenols and their O‐alkylated derivatives were recorded to find the substituent effects of the benzyl, hydroxybenzyl and alkoxybenzyl groups on the ^13^C chemical shifts. It was found that the methylene bridge carbons show signal shifts mainly due to the mesomeric effects of the OH and OCH~3~ substituents, and that in the case of ortho‐substituted benzyl compounds, the methylene carbon signals exhibit upfield shifts due to both mesomeric and steric effects.

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