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Carbon-13 NMR spectroscopy of sulfonium ylides

✍ Scribed by G. Barbarella; P. Dembech; A. Garbesi


Publisher
Elsevier Science
Year
1980
Tongue
French
Weight
230 KB
Volume
21
Category
Article
ISSN
0040-4039

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✦ Synopsis


OZEANO HMXLIA (Bologna)-ITALY C-13 NMB data for a series of stabilized and unstabilized ylides indicate flattening at the ylidic carbon with respect to the Parent salts. For unst*ilired ylides association between the oarbanionic center and the lithium cation cannot be neglected. Sulfunium yfides are the intermediates in the B/D base-catafysed exchange'


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