Several papers have appeared recently dealing with the nmr spectra and chemical exchange processes of phosphonium ylides (1,2,3,4).
Carbon-13 NMR spectroscopy of sulfonium ylides
β Scribed by G. Barbarella; P. Dembech; A. Garbesi
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- French
- Weight
- 230 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
β¦ Synopsis
OZEANO HMXLIA (Bologna)-ITALY C-13 NMB data for a series of stabilized and unstabilized ylides indicate flattening at the ylidic carbon with respect to the Parent salts. For unst*ilired ylides association between the oarbanionic center and the lithium cation cannot be neglected. Sulfunium yfides are the intermediates in the B/D base-catafysed exchange'
π SIMILAR VOLUMES
Recent publications concerned with several different resonance-stabilized sulfonlum ylldes have covered their preparation and spectral properties and synthetic utility but relatively few of thlooarbonyl-stablllzed ylldes have been reported'). We wish to report here a synthesis of some dlthloformate-
This book provides both an introduction for the novice and a review for the expert to the rapidly developing field of 13 C NMR spectroscopy of biological systems. It consists of a forward by Joachim Seelig, a preface by the author, and six chapters dealing with basic principles and key applications.
## Abstract ^13^C NMR spectra of six kawaβpyrones (styryl Ξ±βpyrones) have been assigned. The assignments are based on the splitting pattern in the coupled spectra, comparison of the chemical shifts with those of model compounds and by application of additivity relationships. The ^13^C NMR of styren