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Carbon-13 NMR spectra of some 4-substituted phenacyl chlorides and iodides

✍ Scribed by Paulo Roberto Olivato; Sandra Alvarez Guerrero; Roberto Rittner

Publisher
John Wiley and Sons
Year
1987
Tongue
English
Weight
165 KB
Volume
25
Category
Article
ISSN
0749-1581

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✦ Synopsis

The 13C NMR signals for some 4-substituted phenacyl chlorides and iodides were assigned. The carbonyl carbons exhibit upfield shifts compared with those of the corresponding Csubstituted acetophenones; in the chlorinated derivatives a downfield shift is observed for the cu-methylene carbons, while a reverse effect occurs in the iodinated compounds. The chemical shifts of the aromatic ring carbons are in close agreement with those calculated using substituent chemical shifts.

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