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Carbocupration of cyclopropene. Asymmetric synthesis of quaternary carbon centers

✍ Scribed by Isaka, Masahiko; Nakamura, Eiichi

Book ID
126329224
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
431 KB
Volume
112
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

Asymmetric hetero Diels–Alder route to q
Asymmetric hetero Diels–Alder route to quaternary carbon centers: synthesis of (βˆ’)-malyngolide
✍ Arun K Ghosh; Michio Shirai πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 French βš– 103 KB

Conformationally constrained chiral bis(oxazoline)-metal complex catalyzed asymmetric hetero Diels-Alder reactions of Danishefsky's diene and a variety of Ξ±-keto esters constructed quaternary carbon centers enantioselectively. The reaction was utilized in the synthesis of (-)-malyngolide.