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Asymmetric hetero Diels–Alder route to quaternary carbon centers: synthesis of (−)-malyngolide

✍ Scribed by Arun K Ghosh; Michio Shirai

Book ID
104231284
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
103 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis

Conformationally constrained chiral bis(oxazoline)-metal complex catalyzed asymmetric hetero Diels-Alder reactions of Danishefsky's diene and a variety of α-keto esters constructed quaternary carbon centers enantioselectively. The reaction was utilized in the synthesis of (-)-malyngolide.

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ChemInform Abstract: Asymmetric hetero D
ChemInform Abstract: Asymmetric hetero Diels—Alder Route to Quaternary Carbon Centers: Synthesis of (-)-Malyngolide.
✍ Arun K. Ghosh; Michio Shirai 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 1 views

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