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Carbanion rearrangements. Collison induced dissociations of deprotonated alkyl acetoacetates

โœ Scribed by Peter C. H. Eichinger; John H. Bowie


Book ID
102558592
Publisher
John Wiley and Sons
Year
1987
Tongue
English
Weight
367 KB
Volume
22
Category
Article
ISSN
1076-5174

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Collision-induced dissociations of depro
โœ Mark Eckersley; John H. Bowie; Roger N. Hayes ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 416 KB

The characteristic coUisionLinduced dissociations of (M -HI-ions of dipeptides and tripeptides involve proton transfer to the carboxylate centre as a prelude to fragmentation. Dipeptides show the process + NH,C(R')=C=O (R = H or alkyl) while tripeptides show the analogous processes NH,CH(R')CONHCH(R