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Carbanion rearrangements: Collisionally activated dissociations of deprotonated alkyl malonates

โœ Scribed by Roger N. Hayes; John H. Bowie


Book ID
102557973
Publisher
John Wiley and Sons
Year
1986
Tongue
English
Weight
449 KB
Volume
21
Category
Article
ISSN
1076-5174

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โœ Hamerschmidt, Friedrich ;Hanninger, Achim ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› Wiley (John Wiley & Sons) ๐ŸŒ English โš– 829 KB

Benzyl dialkyl phosphates are deprotonated enantioselec-up to 50%. The pro-(S) hydrogen is removed by amides hatively by homochiral lithium amides of isopropyl( 1-phenyl-ving (S) configuration. Homochiral diethyl (S)-phenyl[D+ ethy1)amine or bis(1-phenylethy1)amine. The short-lived ben-methyl phosph