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Can hydrogen bonds be formed by the addition of a solute to a hydrogen-bonded solvent?

✍ Scribed by A. Ben-Naim

Publisher
Elsevier Science
Year
1972
Tongue
English
Weight
315 KB
Volume
13
Category
Article
ISSN
0009-2614

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✦ Synopsis

A @@al ex&sion.is d&&ed for the' effe$ of a solute ori the average ?umb& of f~y'h~~~~n~~ded mote-:! .

&es ~JI liquid water. Arguments, based on the KirkwoodYBuff iheory of solutions, are given in favor of the conten-.I tiori i!& in LiqiGd water;a simple non-polar solut@may innease the averas number of hydrogen bonds. Fur*Wzr-', '.

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✍ Bart Michielsen; Wouter A. Herrebout; Benjamin J. van der Veken πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 359 KB

## Abstract The complex of halothane (CF~3~CBrClH) with ([D~3~])methyl fluoride is investigated theoretically by means of ab initio calculations at the MP2/6‐311++G(d,p) level and experimentally by infrared spectroscopy of solutions in liquid krypton. The complexation energy is calculated to be βˆ’12