A @@al ex&sion.is d&&ed for the' effe$ of a solute ori the average ?umb& of f~y'h~~~~n~~ded mote-:! . &es ~JI liquid water. Arguments, based on the KirkwoodYBuff iheory of solutions, are given in favor of the conten-.I tiori i!& in LiqiGd water;a simple non-polar solut@may innease the averas number
A classification of hydrogen-bonding solvents by sonic velocity measurements
β Scribed by J. Kenneth Craver
- Publisher
- John Wiley and Sons
- Year
- 1970
- Tongue
- English
- Weight
- 484 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0021-8995
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Proton (deuteron) transfer ofhydrogen bonds in benzoic, glutark and pformylbenzoic acids was studied by proton (deuteron) T, measurements. Deuteration of carboxylic protons was found to increase the barriers to classical proton jumping as well as quantum-mechanical tunneling. The former barriers inc
Hydrogen bonds stabilize protein and nucleic acid structure, but recent results indicate that the amide proton chemical shift little direct spectroscopic data have been available for characterizanisotropy (CSA) varies strongly with hydrogen bond ing these critical interactions in biological macromol
The microwave spectrum of the heterodimer EKYbMF is reported, the collinearity of the nuclei establislIed, and ro(N--F) = 2.796 A obtained. From the Stark effect, ~10 (tiCN4iF) = 5.59 r 0.02 D which indicates an enhancement of 0.78 D over the vector sum of the monomer values.