Solvent effect on the vibrational spectrum of a hydrogen-bonded complex
β Scribed by V.M. Schreiber; D.N. Shchepkin
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 642 KB
- Volume
- 270
- Category
- Article
- ISSN
- 0022-2860
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The Raman spectra of three ring vibrational modes and and the Fermi resonance of ethylene (m 5 , m 6 m 7 ) m 2 -2m 7 carbonate in the solvents TMOS, benzene, methanol and water were studied as a function of concentration at room temperature. The pure dilution e β ect in non-polar solvents, as expecte
## Abstract The broad Ξ³~OH~ bands of some substituted phenols (4βCH~3~, 4βF, 4βBr, 4β1) complexed with tetramethylurea are characterized by a transmission window at about 690 cm^β1^. This window is produced by a resonance interaction of the Ξ³~OH~ and the Ξ½~4~ vibrational levels of the same symmetry