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A Resonance-Window Effect in the γOH Vibration of Some Hydrogen-Bonded Complexes

✍ Scribed by Th. Zeegers-Huyskens

Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
90 KB
Volume
86
Category
Article
ISSN
0037-9646

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✦ Synopsis

Abstract

The broad γ~OH~ bands of some substituted phenols (4‐CH~3~, 4‐F, 4‐Br, 4‐1) complexed with tetramethylurea are characterized by a transmission window at about 690 cm^−1^. This window is produced by a resonance interaction of the γ~OH~ and the ν~4~ vibrational levels of the same symmetry species.

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