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Calculations of V−V Transfer Rates in H 2 and Comparison with Experiment †

✍ Scribed by Kelley, J. D.


Book ID
125844393
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
136 KB
Volume
113
Category
Article
ISSN
1089-5639

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We have measured the HD( o' = 1, J' ) rotational distribution from the D+Hz reaction at a center-of-mass collision energy of about 1.05 eV. The experimental data are compared to distributions derived from two quantum-mechanical (QM) calculations and from a quasiclassical trajectory (QCT) calculation