We present a quasiclassical trajectory study of H + HOD ( v,, ul, Y, ) with an emphasis on how the reaction cross section and the branching between OH and OD products varies with the initial vibrational state of HOD and with relative translational energy. Comparison of the results for initial states
A quasiclassical trajectory study of mode specific reaction rate enhancements in H + H2O (v1v2v3) → OH + H2
✍ Scribed by H. Elgersma; G. C. Schatz
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 462 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0020-7608
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The rate constants for the reactions OH(X 'II, kl k2 u=O) + NH3 --t HzO+ NH? and OII(X '11, u=O) + O3 -HO, + O2 were measured at 296K by the flash photolysis resonance fluorescence technique. The values of the rate constants thus obtained are kl = (4.1 +-0.6) X lo-l4 nndkz = (6.5 t 1.0) X lo-l4 in u
Measurement of the rate of the reaction (1) o ( 3 ~) + H ~( ~ = 0) -+ OH(^ = 0 ) + H is reported. The measurements were made in a flow tube apparatus. The result is based on data for the absolute density of OH(u = 0) obtained from laser-induced fluorescence measurements in the (0-0) hand of the O H