✦ LIBER ✦

The D+H2 reaction: Comparison of experiment with quantum-mechanical and quasiclassical calculations

✍ Scribed by Dahv A.V. Kliner; Klaus-Dieter Rinnen; Richard N. Zare

Publisher: Elsevier Science
Year: 1990
Tongue: English
Weight: 423 KB
Volume: 166
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(90)87260-x

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✦ Synopsis

We have measured the HD( o' = 1, J' ) rotational distribution from the D+Hz reaction at a center-of-mass collision energy of about 1.05 eV. The experimental data are compared to distributions derived from two quantum-mechanical (QM) calculations and from a quasiclassical trajectory (QCT) calculation. We find essentially perfect agreement between experiment and the QM calculations, while the QCT kzsults are-too hot rotationally.

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