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Calculation of the vibronic bandshape of the 2Eg→4A2g phosphorescence in 3d3 complexes

✍ Scribed by J. Kupka

Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
688 KB
Volume
41
Category
Article
ISSN
0009-2614

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✦ Synopsis

CalcuIations of the vibronic bandshape of the 'E o -+ 4Azg transition in octahedral 3d3 complexes are presented. The vibrcmic intensity is expressed in terms of lore&an functions centered around the fundamental odd vibrations of the complex in respect to the 0-O line and weighted by coupling coefficients which enabfe the fitting to the experimental results.

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